Researchers from the University of Michigan developed metal-free phosphorescent OLED emitters
Researchers from the University of Michigan developed metal-free phosphorescent OLED emitters. The idea is that if the emitter molecules cannot vibrate, they cannot release energy and light and so more energy is converted into light. At first they tried creating a stiff lattice (crystalize the emitters) - this achieved 55% light conversion (better than the 25% of regular fluorescent OLEDs, but not as good as the 100% achieved by heavy metal doping).
But this method cannot be adopted for commercial OLEDs easily, and so the second method they tried is to tweaking the organic molecules so that they form structural bonds with a transparent polymer (they attach "like magnets"). This is an easier process, but it achieved only 24% efficiency - similar to a regular fluorescent OLEDs. But they are working on ways to improve this. The important point is that they demonstrated that increasing the intermolecular bonding strength could efficiently suppress the vibrational loss of the phosphorescent light.